Synthesis, Structure, and Reactions of Cluster-Stabilized Phosphaalkenes

✍ Scribed by Dipl.-Chem. Konrad Knoll; Prof. Dr. Gottfried Huttner; Dr. Marek Wasiucionek; Dipl.-Chem. Laszlo Zsolnai

• Publisher: John Wiley and Sons
• Year: 1984
• Tongue: English
• Weight: 246 KB
• Volume: 23
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198407391

✦ Synopsis

tive towards S8, CH2N2, Fez(C0)9, and CS,; 1Oa-c and 11 are formed. Variable temperature 'H-NMR spectro-10 11 a , X = S ; b, X = CHZ; c , X = F e ( C 0 ) 4 scopic studies on 10a-c indicate that a rapid "olefinlike" rotation of the (Me2N)2P-X moiety occurs[' 'I.