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Alternative Synthesis and Structures of C -monoacetylenic Phosphaalkenes

✍ Scribed by Orthaber, Andreas; Öberg, Elisabet; Jane, Reuben T.; Ott, Sascha

Book ID
118767948
Publisher
John Wiley and Sons
Year
2012
Tongue
German
Weight
306 KB
Category
Article
ISSN
0372-7874

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tive towards S8, CH2N2, Fez(C0)9, and CS,; 1Oa-c and 11 are formed. Variable temperature 'H-NMR spectro-10 11 a , X = S ; b, X = CHZ; c , X = F e ( C 0 ) 4 scopic studies on 10a-c indicate that a rapid "olefinlike" rotation of the (Me2N)2P-X moiety occurs[' 'I.