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Synthesis and Structure of the Metalated Zintl Ion[Ge9(μ10-Ge)Ni(PPh3)]2−

✍ Scribed by Donna R. Gardner; Dr. James C. Fettinger; Prof. Bryan W. Eichhorn


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
403 KB
Volume
35
Category
Article
ISSN
0044-8249

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The title compounds, viz. C 13 H 8 (R)Ge (OCHMeCH 2 ) 3 N (1: R = H, 2: R = Me 3 Si; 3: R = Me 3 Ge) were prepared as mixtures of diastereomers by the reaction of N(CH 2 CHMeOSnAlk 3 ) 3 (7: Alk = Et; 8: Alk = Bu) with C 13 H 8 (R)GeBr 3 (4: R = H, 5: R = Me 3 Si; 6: R = Me 3 Ge), respectively. The

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