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Synthesis and Structure of Sb5PO10, a New Phosphate of Antimony(III)

✍ Scribed by Brian A. Adair; Anthony K. Cheetham

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
207 KB
Volume
155
Category
Article
ISSN
0022-4596

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✦ Synopsis

The antimony(III) phosphate, Sb 5 PO 10 , is a framework structure built from vertex-sharing tetrahedral Sb III O 3 E and trigonal bipyramidal Sb III O 4 E moieties (E ‫؍‬ lone pair) and P V O 4 tetrahedral units; orthorhombic, space group P2 1 2 1 2 1 (No. 19), a ‫؍‬ 6.8373(5), b ‫؍‬ 7.0932(5), c ‫؍‬ 19.8730(15) A > , V ‫؍‬ 963.81(12) A > 3 , Z ‫؍‬ 8. The structure, determined by single crystal X-ray di4raction, is based on alternating layers of antimony oxide and antimony phosphate.

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