Synthesis, thermal stability, and crystal structure of antimony(V) phosphate SbOPO4
β Scribed by Y. Piffard; S. Oyetola; A. Verbaere; M. Tournoux
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 368 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-4596
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A new compound, Li 3 AlB 2 O 6 , has been synthesized by solid state reaction and its structure has been solved and re5ned from single-crystal and power X-ray di4raction data. This compound crystallizes in a triclinic unit cell (space group P1 ) with lattice parameters a β«Ψβ¬ 4.876(8) A s , b β«Ψβ¬ 6.1
The antimony(III) phosphate, Sb 5 PO 10 , is a framework structure built from vertex-sharing tetrahedral Sb III O 3 E and trigonal bipyramidal Sb III O 4 E moieties (E β«Ψβ¬ lone pair) and P V O 4 tetrahedral units; orthorhombic, space group P2 1 2 1 2 1 (No. 19), a β«Ψβ¬ 6.8373(5), b β«Ψβ¬ 7.0932(5), c β«