Bisher war lediglich die Struktur des Salzes [Li(thf),][Li{C(SiMe3)3]2]'61 4, cines Organolithiat-Komplexes rnit zweifach-linear koordiniertem Li-Ion bekannt. At-Komplexe werden zwar rnit negativen Ladungen formuliert, enthalten aber dennoch positiv geladene Zentralatome, wie durch MO-Rechnungen fur
Synthesis and Structure of [(OC)4FeSiFe(CO)4 · 2(Me2N)3)PO]—a Complex of Formally Zerovalent Silicon
✍ Scribed by Dr. Christian Zybill; Dr. Dallas L. Wilkinson; Dr. Gerhard Müller
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 242 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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The reactions of [N 3 P 3 (dobp) 2 Cl 2 ] and [N 3 P 3 (dobp)Cl 4 ] with revealed that the complexation of the N atom of one 4oxypyridine ligand by the W(CO) 5 fragment has a a mixture of HOC 5 H 4 N-4 and K 2 CO 3 in acetone give the cyclotriphosphazenes [N 3 P 3 (dobp) 2 (OC 5 H 4 N-4) 2 ] and [N