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Synthesis and Structure of [(OC)4FeSiFe(CO)4 · 2(Me2N)3)PO]—a Complex of Formally Zerovalent Silicon

✍ Scribed by Dr. Christian Zybill; Dr. Dallas L. Wilkinson; Dr. Gerhard Müller


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
242 KB
Volume
27
Category
Article
ISSN
0044-8249

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Bisher war lediglich die Struktur des Salzes [Li(thf),][Li{C(SiMe3)3]2]'61 4, cines Organolithiat-Komplexes rnit zweifach-linear koordiniertem Li-Ion bekannt. At-Komplexe werden zwar rnit negativen Ladungen formuliert, enthalten aber dennoch positiv geladene Zentralatome, wie durch MO-Rechnungen fur

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The reactions of [N 3 P 3 (dobp) 2 Cl 2 ] and [N 3 P 3 (dobp)Cl 4 ] with revealed that the complexation of the N atom of one 4oxypyridine ligand by the W(CO) 5 fragment has a a mixture of HOC 5 H 4 N-4 and K 2 CO 3 in acetone give the cyclotriphosphazenes [N 3 P 3 (dobp) 2 (OC 5 H 4 N-4) 2 ] and [N