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Solid-State and Solution Structures of a Series of [(HBPz3Me2)Rh(CO)(PR3)] and [(HBPz3Me2,4Cl)Rh(CO)(PR3)] Complexes

✍ Scribed by François Malbosc; Valérie Chauby; Carole Serra-Le Berre; Michel Etienne; Jean-Claude Daran; Philippe Kalck


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
464 KB
Volume
2001
Category
Article
ISSN
1434-1948

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✍ Gerhard E. Herberich; Tushar S. Basu Baul; Ulli Englert 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB 👁 2 views

The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th