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Synthesis and structure of a novel tridentate chiral-NHC ligand precursor

✍ Scribed by Yang, Longguang; Cao, Changsheng; Sun, Rui; Peng, Yu; Zhang, Lingzhi; Shi, Zhan; Pang, Guangsheng; Shi, Yanhui


Book ID
120387813
Publisher
Walter de Gruyter GmbH & Co. KG
Year
2011
Tongue
English
Weight
156 KB
Volume
17
Category
Article
ISSN
0793-0283

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Novel chiral tridentate Schiff base liga
✍ Tatyana I. Danilova; Valeria I. Rozenberg; Elena V. Sergeeva; Zoya A. Starikova; πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 268 KB

The first example of the efficient application of chiral tridentate N,O-[2.2]paracyclophane ligands of the imino type for enantioselective diethylzinc addition to aliphatic and aromatic aldehydes is presented. The enantiomeric excess of the resulted secondary alcohols is up to 93% e.e.