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Design and synthesis of novel tridentate and tetradentate chiral ligands

โœ Scribed by Luc Neuville; Jaqueline Chastanet; Jieping Zhu

Book ID
104262236
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
231 KB
Volume
40
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Novel chiral tridentate Schiff base liga
Novel chiral tridentate Schiff base ligands of the [2.2]paracyclophane series: synthesis and application
โœ Tatyana I. Danilova; Valeria I. Rozenberg; Elena V. Sergeeva; Zoya A. Starikova; ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 268 KB

The first example of the efficient application of chiral tridentate N,O-[2.2]paracyclophane ligands of the imino type for enantioselective diethylzinc addition to aliphatic and aromatic aldehydes is presented. The enantiomeric excess of the resulted secondary alcohols is up to 93% e.e.