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Synthesis and Structure of 1-Nitro-4-benzothiazolylsulfanyl- and -sulfonyldienes

✍ Scribed by T.Yu. Kretser; E.S. Lipina; G.A. Berkova; O.I. Evsyukova; N.V. Kuz'mina

Book ID
106523553
Publisher
SP MAIK Nauka/Interperiodica
Year
2005
Tongue
English
Weight
45 KB
Volume
41
Category
Article
ISSN
1070-4280

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## Abstract 1‐(2‐Hydroxyethyl)‐2‐methyl‐5‐nitroimidazole (1) reacts with haloalkyltrialkylsilanes [Hal(CH~2~)~n~SiMe~2~R] to give 4‐nitroimidazole derivatives 3 and acetaldehyde. This process involves at least two reaction steps, __N__‐alkyl quaternization and elimination of the hydroxyethyl group.