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Synthesis and structural study of new rare earth sodium borates Na3Ln(BO3)2 (Ln=Y, Gd)

✍ Scribed by Y Zhang; X.L Chen; J.K Liang; T Xu

Book ID
118603472
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
291 KB
Volume
333
Category
Article
ISSN
0925-8388

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Crystal Structure of Sodium Rare Earth O
Crystal Structure of Sodium Rare Earth Oxyborates Na2Ln2(BO3)2O (Ln=Sm, Eu, and Gd) and Optical Analysis of Na2Gd2(BO3)2O:Eu3+
✍ G. Corbel; M. Leblanc; E. Antic-Fidancev; M. LemaΔ±̂tre-Blaise πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 542 KB

A new structural family of rare earth oxyborates Na 2 Ln 2 (BO 3 ) 2 O (Ln ‫؍‬ Sm, Eu and Gd) is evidenced. The structure, determined by single crystal X-ray diffraction, is monoclinic, space group P2 1 /c, Z ‫؍‬ 4, with a ‫؍‬ 10.695(6) A s , b ‫؍‬ 6.320(4) A s , c ‫؍‬ 10.328(6) A s , ‫؍‬ 117.80(4)Β°