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The crystal chemistry of the new rare-earth sodium borates Na3Ln(BO3)2(Ln = La, Nd)

✍ Scribed by Joëlle Mascetti; Marcus Vlasse; Claude Fouassier


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
395 KB
Volume
39
Category
Article
ISSN
0022-4596

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A new structural family of rare earth oxyborates Na 2 Ln 2 (BO 3 ) 2 O (Ln ‫؍‬ Sm, Eu and Gd) is evidenced. The structure, determined by single crystal X-ray diffraction, is monoclinic, space group P2 1 /c, Z ‫؍‬ 4, with a ‫؍‬ 10.695(6) A s , b ‫؍‬ 6.320(4) A s , c ‫؍‬ 10.328(6) A s , ‫؍‬ 117.80(4)°