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High-Temperature Synthesis, Crystal Structure, and Properties of the New Sodium Rare-Earth Oxide Borates Na2Ln2(BO3)2O (Ln: Dy, Ho).

✍ Scribed by Gunter Heymann; Konstantin Beyer; Hubert Huppertz


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 Β°C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4β€’H2O. The isostructural compounds crystallize in the m