Different synthesis routes have been studied for the preparation of a new oxoalkoxide, Er 2 Ti 4 O 2 (OEt) 18 (HOEt) 2 (Et؍ C 2 H 5 ). The compound was best prepared by reacting KOEt and Ti(OEt) 4 first with water and then with ErCl 3 . The structure was determined by single-crystal X-ray diffract
Synthesis and Structural Investigation of a New Bimetallic Alkoxide with the Composition Mg2Sb4(OC2H5)16
✍ Scribed by U. Bemm; K. Lashgari; R. Norrestam; M. Nygren; G. Westin
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 296 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0022-4596
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A new manganese-antimony oxoethoxide with the formula Mn 7 Sb 4 O 4 (OEt) 18 (HOEt) 2 has been prepared and characterized by single-crystal X-ray diffraction and FT-IR techniques. The structure of the compound has the noncentrosymmetric tetragonal space group symmetry P4 2 (No. 77) with unit-cell pa
The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =