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On the 5-thia-(substituted)-1-oxa-4,6-dithia-5-stibocanes. Synthesis and characterization of O(CH2CH2S)2SbS2P(OC2H5)2 and crystal and molecular structure of (CH2CH2S)2SbSCH2CH2OCH2CH2SSb(SCH2CH2)2O, a compound with two different eight-membered ring conformations

✍ Scribed by Raymundo Cea-Olivares; Miguel-Angel Muñoz-Hernández; Simón Hernández-Ortega; Cristian Silvestru


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
558 KB
Volume
236
Category
Article
ISSN
0020-1693

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The new thioantimonates [CH 3 NH 3 ) 0.5 (NH 4 ) 1.5 Sb 8 S 13 ' 2.8H 2 O (1) and Rb 2 Sb 8 S 13 ' 3.3H 2 O (2) have been hydrothermally synthesized and characterized by single-crystal structure determination. The two compounds are isostructural and crystallize in the monoclinic system, space group