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Synthesis and structural characterization of [(η5-C5Me4)5SiMe2]YCH(SiMe3)2. Hydrogenation to [[(η5-C5Me4)2SiMe2]Y]2(μ2-H)2 and its facile ligand redistribution to Y2[μ2-[(η5-C5Me4)SiMe2(η5-C5Me4)]]2(μ2-H)2

✍ Scribed by E.Bryan Coughlin; Lawrence M. Henling; John E. Bercaw

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
643 KB
Volume
242
Category
Article
ISSN
0020-1693

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3