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Synthesis and structural characterization of zwitterionic oxorhenium(V) complexes with 2-hydroxypyridine

✍ Scribed by Elizeu J. de Souza; Victor M. Deflon; André G. de A. Fernandes; Sebastião S. Lemos; Adelheid Hagenbach; Ulrich Abram


Book ID
118448861
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
278 KB
Volume
359
Category
Article
ISSN
0020-1693

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Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 493 KB 👁 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give