Technetium and rhenium complexes with thioether ligands—IV. Synthesis and structural characterization of binuclear oxorhenium(V) complexes with bidentate thioether coordination
✍ Scribed by Hans-Juergen Pietzsch; Hartmut Spies; Peter Leibnitz; Guenter Reck
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 342 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0277-5387
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📜 SIMILAR VOLUMES
Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give
## Abstract Reaction of WX~6~ (X = Cl or Br) with O(SiMe~3~)~2~ in CH~2~Cl~2~, followed by addition of MeCN and a further equivalent of O(SiMe~3~)~2~ in CH~2~Cl~2~ gives [WO~2~X~2~(MeCN)~2~] in situ, which subsequently react with the dithioethers MeS(CH~2~)~2~SMe, __i__PrS(CH~2~)~2~S__i__Pr or 1,4‐