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Vanadium(IV) and Oxidovanadium(IV) and -(V) Complexes with Soft Thioether Coordination – Synthesis, Spectroscopic and Structural Studies

✍ Scribed by Andrew L. Hector; William Levason; Annie J. Middleton; Gillian Reid; Michael Webster

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
200 KB
Volume
2007
Category
Article
ISSN
1434-1948

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The aminoalcohol ligands diethanolamine (H 2 dea) and triethanolamine (H 3 tea) react with [VO(acac) 2 ] to yield the tetranuclear oxovanadium(IV) complexes [{VO(dea)} 2 -{VO(acac)} 2 (µ 2 -OMe) 2 ] (1) and [{VO(Htea)} 2 {VO(acac)} 2 (µ 2 -OMe) 2 ] (2). In the case of the potentially bridging aminoa