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Synthesis, Spectroscopic and Structural Studies on Six- and Eight-Coordinate Phosphane and Arsane Complexes of Titanium(IV) Halides

✍ Scribed by Richard Hart; William Levason; Bhavesh Patel; Gillian Reid


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
326 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The dichlorodihydridoruthenium (IV) compound [RuH 2 Cl 2 -were obtained. The phenylvinylidene complex [RuCl 2 (=C= CHPh)(PCy 3 ) 2 ] (15) was prepared from phenylacetylene and (PiPr 3 ) 2 ] (4) was prepared from [RuCl 2 (C 8 H 12 )] n (3), PiPr 3 , and H 2 in 2-butanol via the chlorohydridoruthenium

Synthesis, characterization and crystal