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A selenium-bonded oxorhenium(V) complex: solvothermal synthesis, structural characterization, and electrochemical behavior

✍ Scribed by Biswajit Das; Rajesh Chakraborty; Sandipan Sarkar; Ennio Zangrando; Pabitra Chattopadhyay


Book ID
106547862
Publisher
Springer
Year
2011
Tongue
English
Weight
276 KB
Volume
36
Category
Article
ISSN
0340-4285

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Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 493 KB πŸ‘ 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give