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Synthesis and structural characterization of two arsine complexes of silver(I)

✍ Scribed by Corrado Pelizzi; Giancarlo Pelizzi; Pieralberto Tarasconi


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
657 KB
Volume
281
Category
Article
ISSN
0022-328X

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Synthesis and Crystal Structure of a New
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The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2 H)-thione-5-one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 (1). 1 was characterized by IR and 13 C NMR spectroscopy and by an X-ray structure analysis [space group C2/c, Z = 4, lattice dimensions at Β±80 Β°C: a =