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Synthesis and Crystal Structure of a New Silver(I) Complex

✍ Scribed by Forough Adhami; Mitra Ghassemzadeh; Majid M. Heravi; Abas Taeb; Bernhard Neumüller

Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
68 KB
Volume
625
Category
Article
ISSN
0372-7874

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✦ Synopsis

The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2 H)-thione-5-one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 (1). 1 was characterized by IR and 13 C NMR spectroscopy and by an X-ray structure analysis [space group C2/c, Z = 4, lattice dimensions at ±80 °C: a = 1306.7(2), b = 1139.0(2), c = 1089.2(1) pm, b = 94.54(1)°, R 1 = 0.0294]. The cation possesses a highly distorted linear coordination sphere in the solid state.

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