The synthesis of new chiral rhodium complexes and their crystal structures
β Scribed by Min Shi; Gui-Xin Lei
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 141 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.259
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β¦ Synopsis
Abstract
Two novel chiral rhodium complexes were successfully synthesized from the reaction of chiral bidentate nitrogen ligands with RhCl~3~Β·3H~2~O in ethanol under reflux. Their unusual crystal structures were unambiguously obtained by Xβray analysis. Copyright Β© 2001 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2 H)-thione-5-one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 (1). 1 was characterized by IR and 13 C NMR spectroscopy and by an X-ray structure analysis [space group C2/c, Z = 4, lattice dimensions at Β±80 Β°C: a =
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