Synthesis and Characterization of Two New fac-Tricarbonylrhenium(I) Biscarbene Complexes
✍ Scribed by Oliver Hiltner; Eberhardt Herdtweck; Markus Drees; Wolfgang A. Herrmann; Fritz E. Kühn
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 412 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Reaction of the triamidostannates(II) MeSi{SiMe~2~N(__p__‐tol)}~3~SnLi(OEt~2~) (1a) and MeSi{SiMe~2~N(3,5‐xyl)}~3~SnLi(OEt~2~) (1b) with 1/2 molar equiv. of [RhCl(diolefin)]~2~ (diolefin = COD, NBD) and phosphanes, phosphites or isonitriles (“L”) gave the square‐planar complexes [MeSi{S