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Synthesis and Structural Characterization of the [Nb(O)(S2)2SH]2-, [Nb(S)3SH]2-, and {[Nb(S)3]2O}4- anions. New elementary Thio- and Oxothioniobates

✍ Scribed by Mandimutsira, B. S.; Chen, S.-J.; Demadis, K. D.; Coucouvanis, D.


Book ID
120249290
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
308 KB
Volume
34
Category
Article
ISSN
0020-1669

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 German βš– 151 KB πŸ‘ 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4Β± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space