Single crystals of \(\mathrm{Ba}_{3} \mathrm{Nb}_{2} \mathrm{O}_{2} \mathrm{~F}_{12} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) were grown by hydrothermal synthesis in \(\mathrm{HF}\) aqueous solutions. The structure is established from single crystal X-ray diffraction data: S.G. \(C m c 2_{1}, Z=4, a=22.6
✦ LIBER ✦
Synthesis and Crystal Structure of NB Aqua Complex [NB2(µ2-S2)2(H2O)8](CF3SO3)4·2H2O
✍ Scribed by Sokolov, M. N.; Rogachev, A. V.; Abramov, P. A.
- Book ID
- 125363074
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 441 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1040-7278
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Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space