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Synthesis and Crystal Structure of NB Aqua Complex [NB2(µ2-S2)2(H2O)8](CF3SO3)4·2H2O

✍ Scribed by Sokolov, M. N.; Rogachev, A. V.; Abramov, P. A.


Book ID
125363074
Publisher
Springer
Year
2014
Tongue
English
Weight
441 KB
Volume
26
Category
Article
ISSN
1040-7278

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📜 SIMILAR VOLUMES


Ba3Nb2O2F12 · 2H2O: Synthesis and Crysta
✍ M.P. Crosnier-Lopez; J.L. Fourquet 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 195 KB

Single crystals of \(\mathrm{Ba}_{3} \mathrm{Nb}_{2} \mathrm{O}_{2} \mathrm{~F}_{12} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) were grown by hydrothermal synthesis in \(\mathrm{HF}\) aqueous solutions. The structure is established from single crystal X-ray diffraction data: S.G. \(C m c 2_{1}, Z=4, a=22.6

Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space