Synthesis and Crystal Structure of Cs4[Nb2(μ-S2)2(C2O4)4]⋅5H2O
✍ Scribed by A. V. Virovets; M. N. Sokolov; D. Fenske
- Book ID
- 110368615
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2001
- Tongue
- English
- Weight
- 38 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-4766
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Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space
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