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Synthesis and Stereochemistry of exo-4-Aminomethyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene

✍ Scribed by A. O. Kas'yan; E. A. Golodaeva; O. V. Yuzlenko; S. V. Shishkina; O. V. Shishkin; L. I. Kas'yan

Book ID: 111609117
Publisher: SP MAIK Nauka/Interperiodica
Year: 2003
Tongue: English
Weight: 135 KB
Volume: 39
Category: Article
ISSN: 1070-4280
DOI: 10.1023/b:rujo.0000019735.01576.ce

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The synthesis and detailed NMR analysis of diastereoisomerically pure samples of 4-methyltetracyclo[6.2.1.1 3,6 .0 2,7 ]dodec-9-ene-4-carboxylic acid (2), tetracyclo[6.2.1.1 3,6 .0 2,7 ]dodec-9-ene-4-carboxylic acid ( ) and their tert-butyl esters are reported. Mixtures containing two isomers of the