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Synthesis and Stereochemistry of exo-4-Aminomethyltetracyclo [6.2.1.13,6.02,7]dodec-9-ene.

✍ Scribed by A. O. Kas'yan; E. A. Golodaeva; O. V. Yuzlenko; S. V. Shishkina; O. V. Shishkin; L. I. Kas'yan


Publisher
John Wiley and Sons
Year
2004
Weight
119 KB
Volume
35
Category
Article
ISSN
0931-7597

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The synthesis and detailed NMR analysis of diastereoisomerically pure samples of 4-methyltetracyclo[6.2.1.1 3,6 .0 2,7 ]dodec-9-ene-4-carboxylic acid (2), tetracyclo[6.2.1.1 3,6 .0 2,7 ]dodec-9-ene-4-carboxylic acid ( ) and their tert-butyl esters are reported. Mixtures containing two isomers of the