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Synthesis and stereochemistry of bis(cyclopalladium) complexes of 1,1′-bis[1-(arylimino)ethyl]ferrocenes

✍ Scribed by Yang Tie Wu; Yuan Hong Liu; Yang Li; Zhu Qixiu

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
418 KB
Volume
16
Category
Article
ISSN
0277-5387

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1,l'-Bis(methylphenylphosphany1)ferrocene (mppf) (2) was 2)Cr(C0)4 (meso-5) were obtained photochemically from hesynthesized from dilithioferrocene and PMePh(OC6H4-4-xacarbonylchromium and mppf in near quantitative yield. Me). The diastereomers rac-2 and meso-2 were separated by The structures of ra