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Lithiation and phosphorylation of chiral 1,1′-bis(oxazolinyl)ferrocenes

✍ Scribed by Jaiwook Park; Sunwoo Lee; Kyo Han Ahn; Chang-Woo Cho

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
261 KB
Volume
36
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Highly diastereoselective ortho-lithiati
Highly diastereoselective ortho-lithiation of 1,1′-bis-(oxazolinyl)ferrocene directed to C2-symmetric chiral ligands
✍ Wanbin Zhang; Yoichi Adachi; Toshikazu Hirao; Isao Ikeda 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 572 KB

C2-Symmetric 1, l',2,2'-tetrasubstituted ferrocene derivatives are prepared in high yields from chiral 1,1'-bis(oxazolinyl)ferrocenes v/a diastereoselective o,o'-dilithiation with sec-butyUithium followed by nucleophilic substitution. 1, l'-Bis(oxazolinyl)ferrocenes were prepared from 1,1 '-ferrocen