A seven-coordinated tin(IV) complex: dichloro[2,6-diacetylpyridine bis(S-benzyldithiocarbazato-j 5 S,N,N 0 0 0 ,N 0 0 00 0 0 ,S 0 0 0 ]tin(IV) Gerima ´rio F. de Sousa, a \* Jesu ´s Valde ´s Martı ´nez b and Simo ´n Herna ´ndez-Ortega b a
Synthesis and spectroscopy of tin(IV) - S, S′, S″, S″ - tetrakis (isooctylthioglycolate)
✍ Scribed by C.H. Stapfer; R.H. Herber
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 174 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0020-1650
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si
Sulfur homocycles are synthesized from chlorosulfanes in accordance with eq. (a)I". Thus, S, can be prepared from SZCl2, and S9 from S,CI,. Larger rings S,, (n = 11, 13,. . .
In the title complex, [Sn(C~7~H~6~Cl)~2~(C~7~H~13~N~2~S~2~)Cl], the Sn atom is five-coordinate in a trigonal–bipyramidal geometry. One Sn—S bond is markedly longer than the other for the chelating dithiocarbamate ligand.