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Synthesis and spectroscopic and structural characterization of the monomeric diborylphosphine and diphosphinoborane compounds PhP(BMes2)2 and MesB(PPh2)2 (Mes = Mesityl)

✍ Scribed by Bartlett, Ruth A.; Dias, H. V. Rasika; Power, Philip P.


Book ID
127365297
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
477 KB
Volume
27
Category
Article
ISSN
0020-1669

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The reaction of Pt(Me) 2 (cod) (cod = Ξ· 2 :Ξ· 2 -1,5-cyclooctadiene) with 2 equivalents of PPh 2 (OMe) afforded a bis(phosphinite)platinum complex cis-[Pt(Me) 2 {PPh 2 (OMe)} 2 ](1). The reaction of 1 with trifluoromethanesulfonic acid HOTf (OTf -= CF 3 O 2 SO -) and then H 2 O produced a di(aqua)pla