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Synthesis, Spectroscopic Characterization, and Crystal Structure of the Bimetallic Complex [Ni 2 (μ-CO)(CO) 2 (μ-NH(PPh 2 ) 2 ) 2 ]

✍ Scribed by Simón-Manso, Eugenio; Valderrama, Mauricio; Arancibia, Verónica; Simón-Manso, Yamil; Boys, Daphne

Book ID
127160106
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
244 KB
Volume
39
Category
Article
ISSN
0020-1669

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Preparation, Spectroscopic Properties, and Crystal Structures of Fe2(CO)6(μ-CO)(μ-CF2)2, Fe2(CO)6(μ-CO)2(μ-CF2), and Fe2(CO)6(μ-CF2)(PPh3)2 – Theoretical Studies of Methylenic vs. Carbonyl Bridges in Diiron Complexes
✍ W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 253 KB 👁 1 views

The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri