✦ LIBER ✦

Synthesis and Solubility Properties of Methanofullerenes Containing Primary Ammonium Ion Functionalities

✍ Scribed by Luigi Garlaschelli; Dario Pasini; Federica Spiaggia

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 115 KB
Volume: 2005
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200500224

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The synthesis of novel methanofullerene derivatives bearing a primary ammonium ion functionality is described. They are obtained by a Bingel cyclopropanation reaction on C~60~ with malonate esters, bearing both a solubilizing poly(oxyethylene) chain and an aliphatic chain ending with a BOC‐protected amine. After removal of the protecting group, a counterion exchange methodology allows for the introduction of a perfluorinated anion, bringing the overall solubility of these derivatives to 98 mg/mL in an organic CH~2~Cl~2~ solution. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

📜 SIMILAR VOLUMES

Preparation and properties of two new so

Preparation and properties of two new soluble carbazole-containing functional polyacetylenes

✍ Wei Ju Zhu; Zhen Yu Wu; Ji Ming Song; Cun Li 📂 Article 📅 2011 🏛 Chinese Electronic Periodical Services 🌐 English ⚖ 315 KB

Two new functional polyacetylenes bearing carbazole group as pendant, poly{3-[(4-ethynylstyryl)-N-butyl] carbazole}(P1) and poly{3-[4-(prop-2-ynyloxy)phenyl-N-butyl]carbazole}(P2), were prepared using [Rh(nbd)Cl] 2 -Et 3 N as catalyst. The polymers were soluble in common organic solvents such as CHC

Synthesis and ion conductivity of poly(o

Synthesis and ion conductivity of poly(oxyethylene) methacrylates containing a quaternary ammonium group

✍ Fan Yi; Xiaoping Yang; Yongjun Li; Shibi Fang 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

A quaternary ammonium salt of poly(oxyethylene) methacrylates containing a quaternary ammonium group was designed and synthesized as a single-ionic solid polyelectrolyte. The ionic conductivity of the polymer is about 10 À5 S/cm at room temperature. Furthermore, when a small amount of water or aqueo

Synthesis, characterization and biocidal

Synthesis, characterization and biocidal properties of epoxy resins containing quaternary ammonium salts

✍ Nadège Destais; Dominique Adès; Georges Sauvet 📂 Article 📅 2000 🏛 Springer 🌐 English ⚖ 181 KB

Synthesis and thermal properties of solu

Synthesis and thermal properties of soluble silicon containing phenylated aromatic–aliphatic polyamides

✍ A. A. Ghanwat; M. M. Sayyed; P. P. Wadgaonkar; N. N. Maldar 📂 Article 📅 2009 🏛 Springer Netherlands 🌐 English ⚖ 374 KB

High-retention properties for Hg(II) ion

High-retention properties for Hg(II) ions of a resin containing ammonium and pyridine groups

✍ Bernabé L. Rivas; Paulina Ovando; Sandra Villegas 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 19 KB 👁 2 views

High-retention properties for Hg(II) ion

High-retention properties for Hg(II) ions of a resin containing ammonium and pyridine groups

✍ Bernabé L. Rivas; Paulina Ovando; Sandra Villegas 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 100 KB 👁 2 views

## Abstract The metal‐ion uptake behavior of the chelating resin poly([(3‐(methacryloylamino)propyl] trimethyl ammonium chloride‐__co__‐4‐vinyl pyridine) has been investigated. The resin is obtained by radical copolymerization in a yield of 99.6%. The hydrophilic resin shows a high retention capaci