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Preparation and properties of two new soluble carbazole-containing functional polyacetylenes

โœ Scribed by Wei Ju Zhu; Zhen Yu Wu; Ji Ming Song; Cun Li

Publisher
Chinese Electronic Periodical Services
Year
2011
Tongue
English
Weight
315 KB
Volume
22
Category
Article
ISSN
1001-8417

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โœฆ Synopsis

Two new functional polyacetylenes bearing carbazole group as pendant, poly{3-[(4-ethynylstyryl)-N-butyl] carbazole}(P1) and poly{3-[4-(prop-2-ynyloxy)phenyl-N-butyl]carbazole}(P2), were prepared using [Rh(nbd)Cl] 2 -Et 3 N as catalyst. The polymers were soluble in common organic solvents such as CHCl 3 and THF. Their structures and properties were characterized and evaluated with FTIR, 1 H NMR, UV, TGA, GPC, and CV, respectively. The results show that the polymers possess high thermal stability and well hole-injection property.

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