Synthesis and Reactivity of η 5 -Germacyclopentadienyl Complexes of Iron
✍ Scribed by Freeman, William P.; Dysard, Jeffrey M.; Tilley, T. Don; Rheingold, Arnold L.
- Book ID
- 127343327
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 75 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0276-7333
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A series of aryl‐substituted cyclohexadienyliron complexes have been prepared by a general procedure that determines regioselectivity by correctly positioning leaving groups in the precursor complexes. The aryl groups at 1‐C or 2‐C have been shown to be ω directing by the study of react
Chelated dicarbonyl 014-4-methoxycyclohcxadiene) iron complexes 6 and 15 which possess a phosphinilc and a phosphme bridge respectively form a new class of iron complexes. Their cations 5 and 16 reacled regioseleclively with nucleophiles in good yields. The observed regioselectivities are unusual fo