𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and reactivity of α-lithio α-trimethylsilyl cyclopropanes and related derivatives

✍ Scribed by S. Halazy; W. Dumont; A. Krief


Book ID
104235327
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
232 KB
Volume
22
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The preparation and reactions of lithio
✍ Stephen L. Hartzell; Michael W. Rathke 📂 Article 📅 1976 🏛 Elsevier Science 🌐 French ⚖ 158 KB

Lithio tert-butyl bis(trimethylsilyl)acetate, I, obtained by reaction of the corresponding ester, II, with lithium diisopropylamide (es l), reacts with aldehydes to give good yields of a-silylated vinyl esters (eq 2). As suggested previously for the mono-silyl analogue

Synthesis and Reactivity of α,α-Dichloro
✍ Dr. Stefan Jaroch; Dipl.-Chem. Thomas Schwarz; Prof. Dr. Wolfgang Steglich; Dipl 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 240 KB 👁 1 views

nBuLi solution (5 mmol: in hexanej added. On warming to room temperature the original yellow solution changed color from green to reddish-brown. and gdS evolution was observed. After the mixture had been stirred at room temperature for 30 min the resulting clear yellow solution was refrigerated over

Synthesis and polymerization of ethyl α-
✍ Stephen C. Warren; Lon J. Mathias 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 530 KB

## Abstract Ethyl α‐hydroxymethylacrylate (EHMA) was synthesized from ethyl acrylate and paraformaldehyde, and converted to ethyl α‐chloromethylacrylate (ECMA) by reaction with thionyl chloride. ECMA was bulk polymerized at 65°C with α,α′‐azobis(isobutyronitrile) (AIBN) to give a homopolymer with a