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The preparation and reactions of lithio tert-butylbis(trimethylsilyl) acetate. A synthesis of α-silylated vinyl esters.

✍ Scribed by Stephen L. Hartzell; Michael W. Rathke

Book ID: 104226113
Publisher: Elsevier Science
Year: 1976
Tongue: French
Weight: 158 KB
Volume: 17
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93826-7

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✦ Synopsis

Lithio tert-butyl bis(trimethylsilyl)acetate, I, obtained by reaction of the corresponding ester, II, with lithium diisopropylamide (es l), reacts with aldehydes to give good yields of a-silylated vinyl esters (eq 2). As suggested previously for the mono-silyl analogue

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