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Synthesis and reactivity of substituted cyclopentadienyl diphenylphosphido complexes of zirconium(IV). X-ray crystal structure of [(C5H4SiMe 3)2Zr(PPh2)2]

✍ Scribed by Anne-Marie Larsonneur; Robert Choukroun; Jean-Claude Daran; Tomas Cuenca; Juan Carlos Flores; Pascual Royo

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
696 KB
Volume
444
Category
Article
ISSN
0022-328X

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## Abstract The monoalkyl complexes [Zr{Me~2~Si(Ξ·^5^‐C~5~Me~4~)(Ξ·^5^‐C~5~H~3~R)}(Rβ€²)Cl] [R = Me, Rβ€² = CH~2~Ph (1); R = Me, Rβ€² = CH~2~SiMe~3~ (2); R = __i__Pr, Rβ€² = CH~2~Ph (3); R = __i__Pr, Rβ€² = CH~2~SiMe~3~ (4); R = SiMe~3~, Rβ€² = CH~2~Ph (5); R = SiMe~3~, Rβ€² = CH~2~SiMe~3~ (6)] have been synthesiz