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Synthesis and Reactivity of Silicon- and Germanium-Bridged ansa -Cycloheptatrienyl−Cyclopentadienyl Titanium Complexes

✍ Scribed by Tamm, Matthias; Kunst, Andreas; Bannenberg, Thomas; Randoll, Sören; Jones, Peter G.

Book ID
126944430
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
228 KB
Volume
26
Category
Article
ISSN
0276-7333

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The half-sandwich titanium trimethyl complex (η 5 -C 5 H 4 CMe 2 Ar)TiMe 3 (Ar = 3,5-Me 2 C 6 H 3 ) reacts with the Lewis acid B(C 6 F 5 ) 3 to give the ionic Ti IV ansa-cyclopentadienyl-arene complex [(η 5 ,η 6 -C 5 H 4 CMe 2 Ar)TiMe 2 ]-[MeB(C 6 F 5 ) 3 ]. In bromobenzene solvent, addition of more