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Synthesis and reactivity of trimethylsilyl substituted mono(cyclopentadienyl)titanium alkyl complexes

✍ Scribed by J. Saßmannshausen; J. Baumgartner

Book ID
110171135
Publisher
Springer
Year
2009
Tongue
English
Weight
282 KB
Volume
50
Category
Article
ISSN
0023-1584

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Phosphanyl-substituted cyclopentadienes of the type [R n Cp-PR(NR 1 R 2 /Cl)] (1-22) (R = Alk, Ar; R 1 , R 2 = H, Alk, Ar, SiR 3 ; R n Cp = tBuCp, Me 4 Cp, Ind, Me 6 Ind, Flu) can be synthesised by reaction of alkyldichlorophosphanes and alkyl(amino)chlorophosphanes with alkali metal cyclopentadieni