Linked Benzylamido-Cyclopentadienyl Ligands: Synthesis and Characterization of Alkyl Titanium Complexes
โ Scribed by Okuda, Jun ;Eberle, Thomas ;Spaniol, Thomas P.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 820 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
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๐ SIMILAR VOLUMES
Phosphanyl-substituted cyclopentadienes of the type [R n Cp-PR(NR 1 R 2 /Cl)] (1-22) (R = Alk, Ar; R 1 , R 2 = H, Alk, Ar, SiR 3 ; R n Cp = tBuCp, Me 4 Cp, Ind, Me 6 Ind, Flu) can be synthesised by reaction of alkyldichlorophosphanes and alkyl(amino)chlorophosphanes with alkali metal cyclopentadieni
Titanium complexes containing a linked isopropyl-or benz-{C 6 H 4 (CH 2 NMe 2 )-2}Cl and of Ti(ฮท 5 :ฮท 1 -C 5 Me 4 SiMe 2 NiPr)-{CH 2 C 6 H 4 (NMe 2 )-2}Cl revealed the presence of intramolecu-ylamido(tetramethylcyclopentadienyl) ligand C 5 Me 4 Si-Me 2 NR (R = iPr, CH 2 Ph,) and one bidentate organy