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Synthesis, Structure, and Reactivity of ansa -Rhenocene Complexes

โœ Scribed by Heinekey, D. Michael; Radzewich, Catherine E.


Book ID
126070468
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
86 KB
Volume
18
Category
Article
ISSN
0276-7333

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## Abstract We present the synthesis and characterization of disilaโ€ and distanna __ansa__ halfโ€sandwich complexes of Groupโ€…6 transition metals. These compounds exhibit high ring strain within the __ansa__ bridge, which is the key factor for the insertion of elemental chalcogens.