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Synthesis and reactivity of boron difluoride complexes of N,N-dimethylsalicylacetamide

✍ Scribed by Joel Morris; Yue Fang; Donn G. Wishka; Fusen Han


Book ID
108380420
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
285 KB
Volume
34
Category
Article
ISSN
0040-4039

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## Abstract The __ortho__‐palladation of the iminophosphane ligand 6‐phenyl‐2‐[(2,6‐diisopropylphenyl)imino]pyridine (HL) with Pd(OAc)~2~ and PdCl~2~(PhCN)~2~ in benzene yields the neutral Pd–C,N,N pincer complexes Pd(OAc)(κ^3^‐C,N,N‐L) (1) and PdCl(κ^3^‐C,N,N‐L) (2), respectively. In the presence