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N , N -Di-iso-propylcarbamato Complexes of Boron

✍ Scribed by Dell’Amico, Daniela Belli; Calderazzo, Fausto; Labella, Luca; Marchetti, Fabio


Book ID
125960085
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
191 KB
Volume
47
Category
Article
ISSN
0020-1669

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The reaction of [MnCl 2 (thf) 2 ] with the N,N'-dicyclohexylformamidinate anion gave two remarkably different results depending on the nature of the amidinate alkali metal countercation. The reaction with the lithium salt affords a mixed-valence Mn ± oxo cluster [Mn 3 (CyNCHNCy) 6 OLi] ´2 THF (1), f