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Synthesis and reactivity of pyridine N-oxide complexes of cobalt(III)

โœ Scribed by Purcell, William L.


Book ID
120244395
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
579 KB
Volume
28
Category
Article
ISSN
0020-1669

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A series of mixed cobalt(III) complexes [Co(pySe) 3 -n (N N) n ] n + [pySe= pyridine-2-selenolato (1 -); N N= 1,2-ethanediamine (en) and 2,2%-bipyridine (bpy); n= 0, 1 and 2] was prepared. The geometrical preference and trans influence of pySe are fairly different from those of pyridine-2-thiolate.