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Synthesis and reactions of tricyclo[5.2.1.02,6]dec-2(6)-ene

✍ Scribed by Takaishi, Naotake; Takahashi, Hitoshi; Yamashita, Osamu; Inamoto, Yoshiaki


Book ID
121382091
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
577 KB
Volume
51
Category
Article
ISSN
0022-3263

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An efficient enantioselective synthesis of 4-amino-cyclopent-2-ene-l-one 12 from enaminones 8 and and its diastereomer has been accomplished vin a one step 'electron transfer reduction of the enaminone double bond and concomitant removal of an a-methylbenzyl group, followed by a [4 + 21 cycloreversi