Synthesis and Structure Elucidation of 8-Methyl-and 9-Methylexo-2-carbomethoxy-endo-tricyclo(5.2.1.02,6)deca-3,8-dien-5-ones. -The unseparable mixture of 1-and 2-methyl-tetrahydro-1,4-methanonaphthalenediones (I) and (II), resp., obtained by thermal cracking of methylcyclopentadiene dimer and trappi
โฆ LIBER โฆ
ChemInform Abstract: Facial Selectivity in Addition Reactions to the Highly Strained Enone in Tricyclo[5.2.1.02,6]deca-2(6),8-dienone and Tricyclo[5.2.1.02,6]dec-2(6)-enone.
โ Scribed by Antonius J. H. Klunder; Andries A. Volkers; Binne Zwanenburg
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 28 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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## Enzymatic Kinetic Resolution of 5-Hydroxy-4-oxa-endotricyclo(5.2.1.02, 6)dec-8-en-3-ones: A Useful Approach to D-Ring Synthons for Strigol Analogues with Remarkable Stereoselectivity. -Racemic tricyclic hydroxy lactones (I) and (V) are resolved employing a lipase-catalyzed acetylation reaction
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